Capture.PNG

[57]

Gruszka, W.; Haopeng, S.; Buchard, A.; Garden, J. A.

Heterometallic cooperativity in divalent metal ProPhenol catalysts: combining zinc with magnesium or calcium for cyclic ester ring-opening polymerisation

Catal. Sci. Technol., 2021, DOI:10.1039/D1CY01914G.

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[56]

Hall, A. M. R.; Berry, D. B. G.; Crossley; J. N.; Codina, A.; Clegg, I.; Lowe, J. P.; Buchard, A.; Hintermair, U.

Does the Configuration at the Metal Matter in Noyori–Ikariya Type Asymmetric Transfer Hydrogenation Catalysts?

ACS Catalysis, 2021, 11, 13649-13659.

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[55]

Diment, W. T.; Gregory, G. L.; Keer, R. W. F.; Phanopoulos, A.; Buchard, A.; Williams, C. K.

Catalytic Synergy Using Al(III) and Group 1 Metals to Accelerate Epoxide and Anhydride Ring-Opening Copolymerizations

ACS Catalysis, 2021, 11, 12532-12542.

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[54]

McGuire, T. M.; Buchard, A.

Polymers from sugars and CS2: ring opening copolymerisation of a D-xylose anhydrosugar oxetane.

Polymer Chemistry, 2021, 12, 4253-4261.

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[53]

McGuire, T. M.; Clark, E. F.; Buchard, A.

Polymers from Sugars and Cyclic Anhydrides: Ring Opening Copolymerization of a ᴅ-Xylose Anhydrosugar Oxetane.

Macromolecules, 2021, 54, 5094-5105.

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[52]

McGuire, T. M.; Bowles, J.; Deane, E.; Farrar, E. H. E., Grayson, M. N.; Buchard, A.

Control of Crystallinity and Stereocomplexation of Synthetic Carbohydrate Polymers from D‐ and L‐Xylose.

Angew. Chem. Int. Ed., 2021, 60, 4524-4528.

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[51]

Gruszka, W.; Lykkeberg, A; Nichol, G. S.; Shaver, M. P.; Buchard, A; Garden, J. A.

Combining alkali metals and zinc to harness heterometallic cooperativity in cyclic ester ring-opening polymerisation.

Chem. Sci., 2020, 11, 11785-11790.

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[50]

Yuntawattana, N.; McGuire, T. M.; Durr, C. B.; Buchard, A; Williams, C. K.

Indium phosphasalen catalysts showing high isoselectivity and activity in racemic lactide and lactone ring opening polymerizations.

Catal. Sci. Technol., 2020, 10, 7226-7239.

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[49]

McGuire, T. M.; Miyajima, M.; Uchiyama, M.; Buchard, A.; Kamigaito, M.

Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy.

Polym. Chem., 2020, 11, 5844-5850.

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[48]

Piccini, M.; Leak, D. J.; Chuck, C. J.; Buchard, A.

Polymers from sugars and unsaturated fatty acids: ADMET polymerisation of monomers derived from D-xylose, D-mannose and castor oil.

Polym. Chem., 2020, 11, 2681-2691.

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[47]

Howard, I. C.; Hammond, C.; Buchard, A.
Polymer-supported metal catalysts for the heterogeneous polymerisation of lactones.

Polym. Chem., 2019, 10, 5894-5904.

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[46]

McGuire, T. M.; Pérale, C.; Castaing, R.; Kociok-Köhn, G. I; Buchard, A.Monomer

Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer.

J. Am. Chem. Soc., 2019, 141, 13301-13305.

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[45]

Beament, J.; Wolf, T.; Markwart, J. C.; Wurm, F. R.; Jones, M. D.; Buchard, A.

Copolymerization of Cyclic Phosphonate and Lactide: Synthetic Strategies toward Control of Amphiphilic Microstructure.
Macromolecules, 2019, 53, 1220-1226.

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[44]

Thomsett, M. R.; Moore, J. C.; Buchard, A.; Stockman, R. A.; Howdle, S. M. New renewably-sourced polyesters from limonene-derived monomers. 
Green Chem., 2019, 21, 149-156.

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[43]

Yakabi, K.; Jones, A.; Buchard, A.; Roldan, A.; Hammond, C. Chemoselective Lactonization of Renewable Succinic Acid with Heterogeneous Nanoparticle Catalysts.
ACS Sustainable Chem. Eng., 2018, 6, 16341-16351.

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[42]

McGuire, T. M.; López-Vidal, E. M.; Gregory, G. L.; Buchard, A. Synthesis of 5- to 8-membered cyclic carbonates from diols and CO2: A one-step, atmospheric pressure and ambient temperature procedure.
J. CO2 Util., 2018, 27, 283-288.

[41]

Tian, M.; Buchard, A.; Wells, S. A.; Fang, Y.; Torrente-Murciano, L.; Nearchou, A.; Dong, Z.; White, T. J.; Sartbaeva, A.; Ting, V. P. Mechanism of CO2 capture in nanostructured sodium amide encapsulated in porous silica.
Surf. Coat. Technol., 2018, 350, 227-233.

[40]

Beament, J.; Kociok-Köhn, G.; Jones, M. D., Buchard, A. Bipyrrolidine salan alkoxide complexes of lanthanides: synthesis, characterisation, activity in the polymerisation of lactide and mechanistic investigation by DOSY NMR. 
Dalton Trans., 2018, 47, 9164-9172.

[39]

Beament, J.; Mahon, M. F.; Buchard, A.; Jones, M. D. Aluminum Complexes of Monopyrrolidine Ligands for the Controlled Ring-Opening Polymerization of Lactide. 
Organometallics, 2018, 37,1719-1724.

[38]

Buckingham, M. A.; Cunningham, W.; Bull, S. D.; Buchard, A.; Folli, A.; Murphy, D. M.; Marken, F. Electrochemically Driven C−H Hydrogen Abstraction Processes with the Tetrachloro‐Phthalimido‐N‐Oxyl (Cl4PINO) catalyst. 
Electroanalysis, 2018, 30, 1706-1713.

[37]

López-Vidal, E. M.; Gregory, G. L.; Kociok-Köhn, G.; Buchard, A. Polymers from sugars and CS2: synthesis and ring-opening polymerisation of sulfur-containing monomers derived from 2-deoxy-ᴅ-ribose and ᴅ-xylose. Polym. Chem., 2018, 9, 1577-1582.

[36]

Yakabi, K.; Mathieux, T.; Milne, K.; Lopez-Vidal, E. M.; Buchard, A.; Hammond, C. Continuous production of bio-renewable, polymer-grade lactone monomers through Sn-β catalysed Baeyer-Villiger oxidation with H2O2. ChemSusChem, 2017, 10, 3652-3659.

[35]

Romain, C.; Garden, J. A.; Trott,G.; Buchard, A.; White, A. J. P.; Williams, C. K. Di-Zinc Aryl Complexes: CO2 Insertions and Applications in Polymerization Catalysis. Chem. - Eur. J., 2017, 23, 7367-7376.

[34]

Gregory, G. L.; Kociok-Köhn, G.; Buchard, A. Polymers from sugars and CO2: ring-opening polymerisation and copolymerisation of cyclic carbonates derived from 2-deoxy-ᴅ-ribose. Polym. Chem., 2017, 8, 2093-2104.

[33]

Gregory, G. L.; Hierons, E. M.; Kociok-Köhn, G.; Sharma, R. I.; Buchard, A. CO2-Driven stereochemical inversion of sugars to create thymidine-based polycarbonates by ring-opening polymerisation. Polym. Chem., 2017, 8, 1714-1721.

[32]

Gregory, G. L.; López-Vidal, E. M.; Buchard, A. Polymers from sugars: cyclic monomer synthesis, ring-opening polymerisation, material properties and applications. Chem. Commun., 2017, 53, 2198-2217.

[31]

Beament, J.; Mahon, M. F.; Buchard, A.; Jones, M. D. Salan group 13 complexes – structural study and lactide polymerisation. New J. Chem., 2017, 41, 2198-2203.

[30]

Gregory, G. L.; Jenisch, L. M.; Charles, B., Kociok-Köhn, G.; Buchard, A. Polymers from Sugars and CO2: Synthesis and Polymerization of a D-Mannose-Based Cyclic Carbonate. Macromolecules, 2016, 49, 7165-7169.

[29]

Yakabi, K., Milne, K., Buchard, A.; Hammond, C. Selectivity and lifetime effects in zeolite-catalyzed Baeyer-Villiger oxidation investigated in batch and continuous flow. ChemCatChem, 2016, 8, 3490-3498.

[28]

Kirk, S. M.; Quilter, H. C.; Buchard, A.; Thomas, L. H.; Kociok-Kohn, G.; Jones, M. D. Monomeric and dimeric Al(III) complexes for the production of polylactide. Dalton Trans., 2016, 45, 13846-13852.

[27]

Romain, C.; Zhu, Y.; Dingwall, P.; Paul, S.; Rzepa, H. S.; Buchard, A.; Williams, C. K. Chemoselective Polymerizations from Mixtures of Epoxide, Lactone, Anhydride, and Carbon Dioxide. J. Amer. Chem. Soc., 2016, 138, 4120-4131.

[26]

Ahn, S. D.; Fisher, A. C.; Buchard, A.; Bull, S.; Bond, A. M.; Marken, F. Hydrodynamic Rocking Disc Electrode Study of the TEMPO-Mediated Catalytic Oxidation of Primary Alcohols. Electroanalysis, 2016, 28, 2093-2103.

[25]

Ahn, S. D.; Kolodziej, A.; Malpass-Evans, R.; Carta, M.; Mckeown, N. B.; Bull, S.; Buchard, A.; Marken, F. Polymer of Intrinsic Microporosity Induces Host-Guest Substrate Selectivity in Heterogeneous 4-Benzoyloxy-TEMPO-Catalysed Alcohol Oxidations. Electrocatalysis, 2016, 7, 70-78.